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Hydrotalcite framework stabilized ruthenium nanoparticles (Ru/HTaL): efficient heterogeneous catalyst for the
İsmail Burak BaĞuÇ1, Mehmet Yurderİ1, Gülşah Saydan KanberoĞlu1
1Department of Chemistry, Faculty of Science, Van Yüzüncü Yıl University, Van Turkey.
Abstract:
Ruthenium nanoparticles stabilized by a hydrotalcite framework (Ru/HTaL) were prepared by following a 2-step procedure comprising a wet-impregnation of ruthenium(III) chloride precatalyst on the surface of HTaL followed by an ammonia-borane (NH3BH3) reduction of precatalyst on the HTaL surface all at room temperature. The characterization of Ru/HTaL was done by using various spectroscopic and visualization methods including ICP-OES, P-XRD, FTIR, 11B NMR, XPS, BFTEM, and HRTEM. The sum of the results gained from these analyses has revealed the formation of well-dispersed and highly crystalline ruthenium nanoparticles with a mean diameter of 1.27 ±0.8 nm on HTaL surface. The catalytic performance of Ru/HTaL in terms of activity, selectivity, and stability was investigated in the methanolysis of ammonia-borane (NH3BH3 , AB), which has been considered as one of the most promising chemical hydrogen storage materials. It was found that Ru/HTaL can catalyse methanolysis of AB effectively with an initial turnover frequency (TOF) value of 392.77 min-1 at conversion (>95%) even at room temperature. Moreover, the catalytic stability tests of Ru/HTaL in AB methanolysis showed that Ru/HTaL acts as a highly stable and reusable heterogeneous catalyst in this reaction by preserving more than 95% of its initial activity even at the 5th recycle.
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