Enhancing methane production from dewatered waste activated sludge through alkaline and photocatalytic pretreatment

Waste activated sludge generated from wastewater treatment plants makes an abundant source of biomass. Its effective utilization through anaerobic digestion (AD) requires pretreatment to disintegrate the sludge matrix and increase organic matter availability. In this study, dewatered waste activated sludge (DWAS) was subjected to alkaline, photocatalytic, and alkaline-photocatalytic pretreatment for its disintegration and subsequent methane production using different concentrations of sodium hydroxide and titania nanoparticles. Individual pretreatment resulted in maximum disintegration degree (DD_sCOD) of 11.3 and 5.2% at 0.8% NaOH and 0.6 gTiO₂/L, respectively. Alkaline-photocatalytic pretreatment yielded 37% DD_sCOD at 0.8% NaOH-0.4 g/L TiO₂. As compared to control, AD at 0.4% NaOH and 0.5 g/L TiO₂ pretreatments yielded maximum methane, which was 50.4 and 32.6% higher. Similarly, alkaline-photocatalytic pretreatment at 0.4% NaOH-0.5 g/L TiO₂ yielded methane as 462 N mL/g VS, which was 71.1% higher. Modified Gompertz model fitted the methane yield data well.