Related Experiment Video
Updated: Nov 20, 2025

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene
Published on: May 20, 2019
Elemental Sulfur Mediated Novel Multicomponent Redox Polycondensation for the Synthesis of Alternating Copolymers
Hatice Mutlu1, Daniel A Döpping1, Birgit Huber1
1Soft Matter Synthesis Laboratory, Institute for Biological Interfaces 3 (IBG 3), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen, D-76344, Germany.
Abstract:
A sulfur-based self-condensation method is investigated as an efficient tool for the synthesis of polythiophene derivatives. The reaction proceeds through multicomponent redox polycondensation between readily available diketone compounds and elemental sulfur in the presence of a Brønsted acid/base pair. Six different diketone derivatives have been screened and the polymerization is generalized by the synthesis of so-far-unprecedented alternating copolymers based on 2,4-thiophene/arene repeating units. By exploiting microwave heating the synthetic procedure is optimized, particularly for alternating copolymers containing aryl and thiophene units, such that a copolymer can be synthesized in only 24 h compared to the conventional process taking 6 d, yielding polymers within the same apparent weight average molar mass (Mw ). All obtained copolymers are analyzed in detail using size exclusion chromatography (SEC), nuclear magnetic resonance (NMR), attenuated total reflectance infrared spectroscopy (ATR-IR), thermal gravimetric analysis and differential scanning calorimetry (DSC).
More Related Videos
12:30Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
08:51Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
Related Concept Videos
Preparation and Reactions of Sulfides
Thermal and Photochemical Electrocyclic Reactions: Overview
Preparation and Reactions of Thiols
Cycloaddition Reactions: Overview
Thermal Electrocyclic Reactions: Stereochemistry
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
Olefin Metathesis Polymerization: Overview
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...