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Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Unsymmetrical dirhodium single molecule photocatalysts for H2 production with low energy light
Agustin Millet1, Congcong Xue2, Claudia Turro2
1Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA. dunbar@mail.chem.tamu.edu.
Abstract:
New axially blocked unsymmetrical dirhodium complexes photocatalyze the production of H2 under red light irradiation with a turnover number (TON) of 23 ± 3 in the presence of acid and a sacrificial donor. The presence of multiple metal/ligand-to-ligand charge transfer transitions improves their absorption of light into the near-IR.
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