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Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Covalent functionalization of molybdenum disulfide by chemically activated diazonium salts
Lakshya Daukiya1, Joan Teyssandier, Samuel Eyley
1Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven-University of Leuven, Celestijnenlaan, 200 F, 3001 Leuven, Belgium. steven.defeyter@kuleuven.be.
Abstract:
Covalent functionalization is one of the most efficient ways to tune the properties of layered materials in a highly controlled manner. However, molecular chemisorption on semiconducting transition metal dichalcogenides remains a delicate task due to the inertness of their surface. Here we perform covalent modification of bulk and single layer molybdenum disulfide (MoS2) using chemical activation of diazonium salts. A high level of control over the grafting density and yield on MoS2 basal plane can be achieved by this approach. Using scanning probe microscopies and X-ray photoelectron spectroscopy we prove the covalent functionalization of MoS2.
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