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Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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A Molecular Low-Coordinate [Fe-S-Fe] Unit in Three Oxidation States

Christian Schneider1, Serhiy Demeshko2, Franc Meyer2

  • 1Fachbereich Chemie, Philipps-Universität, Hans-Meerwein-Str. 4, 35043, Marburg, Germany.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|January 29, 2021
PubMed
Summary

Researchers synthesized a dinuclear iron complex mimicking the nitrogenase enzyme's active site. This iron-sulfur-iron complex can be reversibly oxidized, offering insights into nitrogenase mechanisms and iron-sulfur cluster chemistry.

Keywords:
57Fe Mössbauer spectroscopyelectrochemistryiron sulfide complexmagnetismnitrogenase

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