Ex-situ XPS analysis of yolk-shell Sb₂O₃/WO₃ for ultra-fast acetone resistive sensor

The preparation of fast, highly responsive and reliable gas sensing devices for the detection of acetone gas is considered to be a key challenge for the development of accurate disease diagnosis systems through exhaled respiratory gases. In the paper, yolk shell Sb₂O₃/WO₃ is synthesized and its gas sensing performance was studied by static test system. Special, the maximum response value of 1:1 Sb₂O₃/WO₃ yolk-shell (WO₃-1 YSL) sensor to 100 ppm acetone can reach as high as 50.0 at 200 ℃. And it also exhibits excellent response/recover time (4 s/5 s), low detection limit (2 ppm) and superior selectivity towards acetone. More importantly, in mixed selective gas test, the sensor shows high selectivity towards acetone. And the mechanism is analyzed by ex-situ XPS. The excellent gas-sensing performance can be attributed to unique yolk-shell structure, which facilitates the rapid transport of charge carriers from the surface to the bulk and provides more active sites for gas adsorption and desorption; the heterojunction between of Sb₂O₃ and WO₃, which promotes oxygen pre-adsorption on the surface and increasing the interfacial potential; the increased oxygen vacancies which allowing more chemisorbed oxygen to form.