Simple and efficient fabrication of multi-stage color-changeable photonic prints as anti-counterfeit labels

Color changeable photonic prints (CCPPs) show their potential applications in high-level information storage and anti-counterfeiting, but usually suffer from the complex fabrication process and limited color variation. Here, a simple and efficient method is developed to generate CCPPs with multilevel tunable color contrasts by packing the solvent responsive photonic crystals with diverse cross-linking degrees and desired way. The key to the successful fabrication is to create and control over the optical response of each part of the CCPPs through altering the cross-linking degree of PCs and thus the affinity between the CCPPs and solvents. A CCPPs based anti-fake label with the encrypted information functionality which originates from reversible color change between dried state and swelling with the mixture of acetic acid and ethanol is investigated. Compared with conventional CCPPs, the as-prepared CCPPs can reveal multistage information depending on the volume fraction of ethanol. This work provides a new insight for the simple fabrication of CCPPs and will facilitate their applications in the information protection and high-level anti-counterfeiting.