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Published on: June 8, 2016
Preparation of Block Copolymer Nano-Objects with Embedded β-Ketoester Functional Groups by Photoinitiated RAFT
Jiayuan Huang1, Dongdong Liu1, Ying Chen2
1Department of Polymeric Materials and Engineering, School of Materials and Energy, Guangdong University of Technology, Guangzhou, 510006, China.
Abstract:
Herein, a photoinitiated reversible addition-fragmentation chain transfer (RAFT) dispersion polymerization of 2-(acetoacetoxy)ethyl methacrylate (AEMA) in ethanol/water at room temperature for in situ preparation of β-ketoester-functionalized block copolymer nano-objects is reported. AEMA is also copolymerized with isobornyl methacrylate (IBOMA) to improve the colloidal stability of PIBOMA-based block copolymer nano-objects prepared by photoinitiated RAFT dispersion polymerization at low temperatures. A series of P(IBOMA-stat-AEMA)-based block copolymer nano-objects are prepared by changing reaction parameters. Finally, lanthanide-doped block copolymer nano-objects with luminescent and magnetic properties are also prepared based on the complexation of various lanthanide ions with the β-ketoester group. It is expected that the current study will provide a facile platform for the in situ preparation of β-ketoester-functionalized block copolymer nano-objects with different morphologies for specific applications.
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