Ligands as copper and nickel ionophores: Applications and implications on wastewater treatment

Modern society depends on many finite natural resources, from which metals are of great importance. Copper and nickel's relevance is due to their vast applications, resulting in high market value and demand. As such, their polluting emissions are also significant and their removal from wastewaters is imperative. Moreover, effluent treatment techniques can be used to recover the metallic cations, via selective processes. In this review, copper and nickel selective ligands in the literature are surveyed. These are most commonly Schiff bases, along with crown ethers and porphyrins. They are usually employed in ion sensing (colorimetric chemosensors or electrodes) with great success - the disruption in response of colorimetric sensors is up to 7% and binding constants are usually at least one order of magnitude greater with the desired cation than with interferents. However, modified adsorbents are also reported. The possibilities of using ionophores in wastewater cleaning, allowing the treatment of effluents and the selective recovery of valuable materials, and their implications on new green policies is discussed.