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Efficient Photoelectrochemical Conversion of Methane into Ethylene Glycol by WO3 Nanobar Arrays
Jun Ma1,2, Keke Mao3, Jingxiang Low1
1Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, National Synchrotron Radiation Laboratory, and CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei, Anhui, 230026, China.
Abstract:
Photoelectrochemical (PEC) conversion of methane (CH4 ) has been extensively explored for the production of value-added chemicals, yet remains a great challenge in high selectivity toward C2+ products. Herein, we report the optimization of the reactivity of hydroxyl radicals (. OH) on WO3 via facet tuning to achieve efficient ethylene glycol production from PEC CH4 conversion. A combination of materials simulation and radicals trapping test provides insight into the reactivity of . OH on different facets of WO3 , showing the highest reactivity of surface-bound . OH on {010} facets. As such, the WO3 with the highest {010} facet ratio exhibits a superior PEC CH4 conversion efficiency, reaching an ethylene glycol production rate of 0.47 μmol cm-2 h-1 . Based on in situ characterization, the methanol, which could be attacked by reactive . OH to form hydroxymethyl radicals, is confirmed to be the main intermediate for the production of ethylene glycol. Our finding is expected to provide new insight for the design of active and selective catalysts toward PEC CH4 conversion.
