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Overcoming thermal quenching in upconversion nanoparticles.

Yanze Wang1, Bing Chen1, Feng Wang1

  • 1Department of Materials Science and Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Hong Kong SAR, China. fwang24@cityu.edu.hk and City University of Hong Kong Shenzhen Research Institute, Shenzhen 518057, China.

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Thermal quenching reduces light emission in luminescent materials. This review explores energy transfer mechanisms in upconversion nanoparticles to overcome this challenge for technological applications.

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Optics

Background:

  • Thermal quenching, a loss of light emission with rising temperature, hinders luminescent materials.
  • This phenomenon is particularly problematic for upconversion nanoparticles used in lighting, displays, and imaging.
  • Upconversion processes are susceptible due to temperature-dependent intra-particle energy transfer.

Purpose of the Study:

  • To discuss the fundamental origin of thermal quenching in luminescent materials.
  • To elucidate the specific role of energy transfer in thermal quenching phenomena.
  • To summarize recent advancements in mitigating thermal quenching in upconversion nanoparticles.

Main Methods:

  • Literature review of thermal quenching mechanisms.
  • Analysis of energy transfer pathways in upconversion nanoparticles.
  • Synthesis of recent research on overcoming thermal quenching.

Main Results:

  • Thermal quenching originates from temperature-dependent processes affecting energy transfer.
  • Engineering energy transfer routes is a key strategy to combat thermal quenching.
  • Various methods have been developed to enhance thermal stability of upconversion nanoparticles.

Conclusions:

  • Understanding energy transfer is crucial for addressing thermal quenching.
  • Advanced strategies in engineering energy transfer routes show promise.
  • Overcoming thermal quenching will enable wider technological adoption of upconversion nanoparticles.