Flexible Transparent Polypyrrole-Decorated MXene-Based Film with Excellent Photothermal Energy Conversion Performance

Flexible transparent heaters based on photothermal energy conversion are highly desired for next-generation electronic devices. However, how to balance the photothermal conversion efficiency and transparency is still a huge challenge. In this work, we demonstrate a flexible polycarbonate (PC) film with balanced photothermal energy conversion performance and transparency obtained from the spraying polypyrrole (PPy)-modified Ti₃C₂T MXene (MXene@PPy) layer. Due to the synergistic light-to-heat effects of MXene and the attached PPy nanoparticles, the resulted transparent film heater (MP-PC) can obtain a satisfying photothermal conversion performance (47.5 °C at 100 mW/cm²) at a low spraying density of MXene and thus show an effective transmittance of 51.61%, simultaneously. Moreover, the photothermal conversion performance reveals an outstanding stability without significant deterioration after exposing to an outdoor environment for seven months. Besides, arising from the excellent surface electrical resistance (413 Ω/sq), the MP-PC film also exhibits an effective Joule heating capacity with a high heating temperature of 108 °C at 24 V input voltage. As one of the promising applications, the MP-PC film exhibits the effectiveness and feasibility as a light-triggered thermal therapy film for human skin in cold environments.