Z-Scheme Photocarrier Transfer Realized in Tungsten Oxide-Based Photocatalysts by Combining with Bismuth Vanadate...

Multicomponent photocatalysts with a Z-scheme charge transfer are promising in converting solar to hydrogen fuel because of their significantly improved light absorption and restrained photocarrier recombination while keeping their redox capacity. In this work, a composite photocatalyst of BiVO₄ quantum dot-decorated WO₃ nanosheet arrays was synthesized and investigated. The existence of the Z-scheme charge transfer behavior was confirmed by the redox probe technique. Such a Z-scheme charge transfer makes it possible to generate hydrogen without bias. An optimized photocatalyst produces a hydrogen generation rate of 0.75 μmol/h without bias and a photocurrent of 1.91 mA/cm² at 1.23 V versus RHE, which is about 70% higher than that of pure WO₃. We attributed these improvements to the enhanced light absorption, extended conduction band level of BiVO₄, as well as the unique charge transfer behavior in the Z-scheme structure. This work presents a generalizable method to improve the redox capacity of a variety of semiconductors through rationally selecting the building material blocks in view of energy levels.