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Radiative lifetime-encoded unicolour security tags using perovskite nanocrystals
Sergii Yakunin1,2, Jana Chaaban3, Bogdan M Benin4,5
1Institute of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, Zürich, Switzerland. yakunins@ethz.ch.
Nature Communications
|February 13, 2021
Summary
New security tags use tunable perovskite nanocrystals for anticounterfeiting. These tags offer multi-fluorescent-lifetime encoding, enhancing security beyond traditional methods for better product protection.
Area of Science:
- Materials Science
- Nanotechnology
- Optics
Background:
- Traditional anticounterfeiting tags rely on basic visual identification, making them vulnerable to sophisticated fraud.
- Advanced security features like fluorescent lifetime and pattern masking are needed to deter counterfeiting effectively.
Purpose of the Study:
- To develop a novel unicolour multi-fluorescent-lifetime security tag system using electrohydrodynamically printed perovskite nanocrystals.
- To demonstrate the efficacy of these tags against conventional readers and their decipherability with advanced imaging techniques.
Main Methods:
- Synthesis of lifetime-tunable lead-halide perovskite nanocrystals via cation-engineering (formamidinium for ethylenediammonium substitution).
- Electrohydrodynamic printing of perovskite nanocrystals into fluorescence-lifetime-encoded tags.
- Deciphering tag information using time-correlated single-photon counting fluorescence-lifetime imaging microscopy and a novel time-of-flight prototype.
Main Results:
- Successfully prepared unicolour, lifetime-tunable perovskite nanocrystals with matching emission wavelengths.
- Demonstrated that printed tags are resistant to conventional reading methods.
- Validated the use of both established and a novel portable time-of-flight prototype for deciphering the fluorescence lifetime codes.
Conclusions:
- The developed perovskite nanocrystal-based security tags offer a robust anticounterfeiting solution with enhanced security features.
- The combination of novel material synthesis, advanced printing, and portable deciphering technology provides a comprehensive approach for product protection.
- This innovation has the potential to safeguard both producers and consumers from counterfeit goods.

