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Boron-enriched polyvinyl-alcohol/boric-acid nanoparticles for boron neutron capture therapy

Wei-Jen Chan1, Han-Lin Cho2, Venkanagouda Goudar2

  • 1Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan.

Nanomedicine (London, England)
|February 18, 2021
PubMed

Keywords:
PVAboric acidboron neutron capture therapyhead and neck cancernanomedicine

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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.