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Updated: Nov 17, 2025

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

Copper(i)-iodide cluster structures as functional and processable platform materials.

Javier Troyano¹, Félix Zamora, Salomé Delgado

¹Institute for Integrated Cell-Material Sciences (WPI-iCeMS) Kyoto University Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.

Chemical Society Reviews

|February 18, 2021

Summary

This summary is machine-generated.

Copper(I) iodide (CuI) combined with organic ligands creates diverse structures with tunable light emission. These materials show promise for organic light-emitting diodes and optical sensors.

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Area of Science:

Coordination Chemistry
Materials Science
Photophysics

Background:

Copper(I) iodide (CuI) and organic ligands form diverse polynuclear structures.
These materials exhibit tunable emission properties, crucial for optoelectronic applications.

Purpose of the Study:

To review advances in CuI-based materials.
To rationalize structures into molecular complexes and extended networks.
To highlight material processability for device integration.

Main Methods:

Literature review of CuI coordination chemistry.
Analysis of structural dimensionality (molecular vs. extended).
Evaluation of physicochemical properties and preparation methods.

Main Results:

CuI-organic ligand combinations yield varied molecular and extended structures.
Emission properties are controllable via chemical structure and composition.
Processability is a key factor for device applications.

Conclusions:

CuI-based materials offer significant potential for organic light-emitting diodes and optical sensors.
Understanding structure-property relationships is vital for future device development.
This field integrates coordination chemistry with materials science for technological advancement.