Unravelling the Structure of a Medium-Sized Metalloid Gold Nanocluster and its Filming Property

Unravelling the structure of thiolated metalloid gold nanoclusters in the medium-sized range by single crystal X-ray crystallography (SCXC) is challenging. Herein, we successfully synthesized a novel Au₆₇ (SR)₃₅ nanocluster, and unravelled its single crystal structure by SCXC, which features a mix-structured Au₄₈ kernel protected by one Au₄ (SR)₅ staple and fifteen Au(SR)₂ staples. Unprecedentedly, this structure can be thermally induced to aggregate into larger nanoparticles and self-deposit to form a gold nanoparticles film onto the walls of a vial or other substrates such as quartz, mica or ceramic, which can be developed into a facile, substrate-universal and scalable filming method. The film exhibits high sensitivity, uniformity and recyclability as a surface-enhanced Raman scattering (SERS) substrate and can be applied for detecting multiple organic pollutants.