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Updated: Nov 15, 2025
Stable Aqueous Suspensions of Manganese Ferrite Clusters with Tunable Nanoscale Dimension and Composition
Published on: February 5, 2022
Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building
Uttam Chakraborty1, Patrick Bügel2, Lorena Fritsch3
1Dept. of Chemistry, University of Hamburg Martin Luther King Pl. 6, 20146, Hamburg, Germany.
Abstract:
The controlled assembly of well-defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D-structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide). The structures and properties of isolated Fe4 , Fe6 , and Fe7 nanoplatelets and calculated intermediates enable an unprecedented insight into the underlying building principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles.
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