Stacking nuances modulate the mechanical properties of graphene/SnO₂nanocomposites

Due to its superior mechanical properties, graphene is widely used as reinforcement materials in nanocomposites. In this work, a series of indentation simulations was performed, using finite element method, to investigate the mechanical properties of graphene/TiO₂and graphene/SnO₂nanocomposite films. The force-displacement curves obtained from simulations were first compared to analytical results, which demonstrates that with increasing the thicknesses of metal oxide layers, the mechanical responses of nanocomposites exhibit a transition from non-linear behaviors to linear behaviors. Furthermore, consistent with literature works, increasing graphene volume fraction can enhance the Young's modulus of the corresponding heterostructure. Interestingly, this enhancement can be modulated by nuances in stacking orders, i.e. layer arrangements, of nanocomposites. Through analyzing stress and strain distributions, the underlying mechanisms were proposed. Our results reported here provide comprehensive characterizations and understandings on the reinforcement effects of graphene on graphene/metal oxide nanocomposites.