Decomposition of gaseous chlorobenzene using a DBD combined CuO/α-Fe₂O₃ catalysis system

Copper oxide and hematite (CuO/α-Fe₂O₃) composite catalysts were prepared by using goethite as precursor adopted impregnation way and applied to the dielectric barrier discharge (DBD) catalytic decomposition of gaseous chlorobenzene. The CuO/α-Fe₂O₃ composite was characterised by X-ray diffraction, Brunauer-Emmett-Teller method, scanning electron microscopy and X-ray photoelectron spectrometer technique. The decomposition efficiency and energy yield of gaseous chlorobenzene in DBD catalysis system were studied by a function of gas flow rate, initial concentration and input voltage. The results showed that the CuO/α-Fe₂O₃ composite catalyst exhibited remarkable performance on chlorobenzene decomposition when the molar ratio was 0.4 and calcination temperature was 450°C. When the chlorobenzene initial concentration was 230 mg m^-3, the chlorobenzene decomposition efficiency and mineralisation rate on the DBD catalysis system reached 73.33% and 63.37%, respectively, its decomposition and mineralisation efficiency were enhanced about 20.5% and 16.61%, respectively, compared with the bare DBD system, and it also benefited to significantly reduce the ozone and NO₂ by-products. The possible pathway of chlorobenzene decomposition in the DBD catalytic hybrid system was proposed based on the products analysis.