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Related Concept Videos

Types of Step-Growth Polymers: Polyesters01:20

Types of Step-Growth Polymers: Polyesters

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The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the polymer...
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Anionic Chain-Growth Polymerization: Overview01:20

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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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Polymers02:34

Polymers

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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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Step-Growth Polymerization: Overview01:03

Step-Growth Polymerization: Overview

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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
Many natural and synthetic polymers are produced by...
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Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
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Cycloaddition Reactions: Overview01:16

Cycloaddition Reactions: Overview

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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Related Experiment Video

Updated: Nov 15, 2025

Transport Properties of Ibuprofen Encapsulated in Cyclodextrin Nanosponge Hydrogels: A Proton HR-MAS NMR Spectroscopy Study
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Research Progress on Synthesis and Application of Cyclodextrin Polymers.

Yuan Liu1, Ting Lin1, Cui Cheng1

  • 1College of Biological Science and Engineering, Fuzhou University, Fuzhou 350108, China.

Molecules (Basel, Switzerland)
|March 6, 2021
PubMed
Summary

High molecular weight cyclodextrin polymers (pCDs) offer enhanced stability and retain the unique cavity structure of cyclodextrins (CDs). This review covers pCD synthesis and applications in separation science, materials, and biomedicine.

Keywords:
biomedicinecyclodextrin polymersmaterials scienceseparation sciencesynthesis

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Area of Science:

  • Polymer Science
  • Supramolecular Chemistry
  • Analytical Chemistry

Background:

  • Cyclodextrins (CDs) are cyclic oligosaccharides with characteristic hydrophobic cavities.
  • Modification of CDs yields high molecular weight cyclodextrin polymers (pCDs).
  • pCDs combine CD cavity properties with polymer stability.

Purpose of the Study:

  • To review the synthesis of cyclodextrin polymers (pCDs).
  • To highlight the applications of pCDs in various scientific fields.
  • To discuss the potential of pCDs as functional polymer materials.

Main Methods:

  • Polymerization, substitution, and grafting techniques are used for pCD synthesis.
  • Characterization of pCDs focuses on their structural and functional properties.
  • Literature review of pCD research progress.

Main Results:

  • pCDs exhibit enhanced stability compared to native CDs.
  • The internal hydrophobic and external hydrophilic cavity structure is retained in pCDs.
  • pCDs have demonstrated significant potential in analytical separation, materials science, and biomedicine.

Conclusions:

  • Cyclodextrin polymers (pCDs) are versatile functional materials.
  • pCDs offer a promising platform for advanced applications.
  • Further research into pCD synthesis and applications is warranted.