Remote estimates of CDOM using Sentinel-2 remote sensing data in reservoirs with different trophic states across...

Chromophoric dissolved organic matter (DOM) is called as CDOM which could affect the optical properties of surface waters, and is a useful parameter for monitoring complex inland aquatic systems. Large-scale monitoring of CDOM using remote-sensing has been a challenge due to the poor transferability of CDOM retrieval models across regions. To overcome these difficulties, a study is conducted using Sentinel-2 images, in situ reflectance spectral data, and water chemical parameters at 93 water reservoirs across China classified by trophic state. Empirical algorithms are established between CDOM absorption coefficient a_CDOM(355) and reflectance band ratio (B5/B2,vegetation Red Edge/Blue) acquired in situ and via Sentinel-2 MSI sensors. Relationships are stronger (r² > 0.7, p < 0.05) when analysis is conducted separately by trophic states. Validation models show that, by accounting for trophic state of reservoirs and using B5/B2 band ratios, it is possible to expand the geographical range of remote sensing-based models to determine CDOM. However, the accuracy of model validation decreased from oligotrophic (r²: 0.86) to eutrophic reservoirs (r²: 0.82), likely due to increased complexity of CDOM sources in nutrient-rich systems. This study provides a strategy for using local and remote-sensing data to monitor the spatial variations of CDOM in reservoirs based on different trophic states, and will contribute to water resources management.