Facile fabrication of (2D/2D) MoS₂@MIL-88(Fe) interface-driven catalyst for efficient degradation of organic...

The present investigation describes the photocatalytic degradation of methylene blue (MB) and rhodamine-B (RhB) using molybdenum disulfide (MoS₂) anchored metal-organic frameworks (MOFs) under visible light irradiation. Herein, MIL-88(Fe) was successfully modified with MoS₂ to yield a novel heterogeneous MoS₂@MIL-88(Fe) hybrid composite. The prepared catalyst enhances the superior photocatalytic activity than the pristine form of MoS₂ and MIL-88(Fe) framework. The physico-chemical properties of the prepared catalyst were analytically investigated and the results exhibit greater photocatalytic efficiency towards the chosen dyes, with an optical band gap of 2.75 eV. The MoS₂ and MIL-88(Fe) framework could act as efficient oxidation and reduction sites in the as-synthesized MoS₂@MIL-88(Fe) composite, and generated the non-toxic by-products such as hydroxyl ^(•OH), and superoxide species ^(•O₂^-) for the mineralization of MB and RhB dyes. The degradation kinetics showed that the dye system followed a pseudo-first-order model which is well supported by the Langmuir-Hinshelwood mechanism. Moreover, the reusability studies showed excellent photocatalytic activity after five cycles. Finally, the photocatalytic degradation mechanism of MB and RhB dyes was suggested.