Low-pressure multipass Raman spectrometer

Nonintrusive, quantitative measurements of thermodynamic properties of flows associated with propulsion systems are pivotal to advance their design and optimization. Laser-based diagnostics are ideal to provide quantitative results without influencing the flow; however, the environments in which such flows exist are often not conducive for such techniques. Namely, they often lack the optical accessibility required to facilitate the delivery of incident laser radiation and the subsequent collection of induced signals. A particularly challenging, yet crucial, task is to measure thermodynamic properties of plumes issuing from thrusters operating within a vacuum chamber. Large chambers used to simulate the vacuum of space generally lack optical ports that can facilitate complex laser-based measurements. Additionally, the near-vacuum environments within such chambers coupled with the ability of thrusters to efficiently expand the gas flowing through their nozzles lead to plumes with prohibitively low number densities (pressures below 1 Torr). Thus, there is a need to develop a diagnostic system that can offer high throughput without the use of free-space optical ports. Moreover, facilities where propulsion systems are tested typically lack vibrationally isolated space for diagnostic equipment and accurate climate control. As a result, such a high-throughput system must also be compact, versatile, and robust. To this end, the present work describes a fiber-coupled, multipass cell, spontaneous Raman scattering spectroscopy system. This system is intended to provide accurate temperature measurements within low-pressure environments via H₂ rotational Raman thermometry. Proof-of-principle measurements are successfully performed at pressures as low as 67 Pa (500 mTorr). Techniques to maintain the signal-to-noise ratio at lower pressures, and the trade-offs associated with them, are discussed and evaluated. Finally, the ability of this system to facilitate additional quantitative measurements is also discussed.