Controllable Design of Bifunctional VO₂ Coatings with Superhydrophobic and Thermochromic Performances

The structure and functions of natural organisms provide great inspirational sources for designing and manufacturing bionic coatings, which hold a distinguished scientific promise to tackle challenges facing humans. In this work, we report a facile and controllable approach to prepare various hexagonal periodic array VO₂ thin films by simply manipulating the speed of the dip-coating operation. The hexagonal cellular-structured VO₂ surface delivered the best thermochromic performance with a T_lum of 79.34% and a ΔT_sol of 9.87%. Impressively, superhydrophobic and thermochromic properties could be integrated into hexagonal semi-dome thin films (with a T_lum of 70.9%, a ΔT_sol of 9.3%, and a water contact angle of 150°) without any post-treatment by low-surface-energy chemicals, which hold considerable potential for application in multifunctional smart windows. Moreover, based on the Cassie-Baxter mode and finite-difference time-domain calculations, the dependence of the thermochromic and wettability performances on the VO₂ structure has been investigated in this study.