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Updated: Nov 14, 2025

TiO2-coated Hollow Glass Microspheres with Superhydrophobic and High IR-reflective Properties Synthesized by a Soft-chemistry Method
Published on: April 26, 2017
Facile Synthesis of Transparent Glass Surfaces via Hydrothermal Route for Superhydrophobic Performance
Umbreen Fatima1, Muhammad Zafar2, Asad Ullah Khan1
1Department of Chemical Engineering, Commission on Science and Technology for Sustainable Development in the South University Islamabad, Lahore 54000, Pakistan.
Abstract:
A facile and peculiar synthesis strategy is designed for the fabrication of transparent superhydrophobic surfaces on simple glass substrate. The synthesis methodology comprises of two steps of hydrothermal treatment of cleaned glass substrate with ultrapure water as a solvent followed by coating of 1H, 1H, 2H, 2H-perflourooctyltriethoxysilane (POTS) also by hydrothermal treatment in hydrothermal reactor. The hydrothermal treatment of glass substrate lead to the nanostructured surface morphology consisting of nanofibers and a blend of nanofibers/nanoflakes. Aforesaid nanostructured surface morphology upon hydrophobic coating resulted in superhydrophobic properties, increasing the water contact angle (WCA) from 92.0° to as high as 145.3°. Moreover, the developed synthesis approach also resulted in the optical transparent superhydrophobic glass substrate thus offering an attractive methodology to employ for self-cleaning applications.

