Related Experiment Video
Updated: Nov 13, 2025

Engineering Molecular Recognition with Bio-mimetic Polymers on Single Walled Carbon Nanotubes
Published on: January 10, 2017
Chiral Detection with Coordination Polymers
1School of Chemistry, The University of Melbourne, Parkville, Victoria, 3010, Australia.
Abstract:
Coordination polymers and metal-organic frameworks are prime candidates for general chemical sensing, but the use of these porous materials as chiral probes is still an emerging field. In the last decade, they have found application in a range of chiral analysis methods, including liquid- and gas-phase chromatography, circular dichroism spectroscopy, fluorescence sensing, and NMR spectroscopy. In this minireview, we examine recent works on coordination polymers as chiral sensors and their enantioselective host-guest chemistry, while highlighting their potential for application in different settings.
More Related Videos
10:52Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
Published on: July 27, 2022
09:22Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Related Concept Videos
Prochirality
Chirality at Nitrogen, Phosphorus, and Sulfur
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
Chirality
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
Chirality in Nature
Stereoisomerism
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
Molecules with Multiple Chiral Centers