Related Experiment Video
Updated: Nov 13, 2025

Precise Electrochemical Sizing of Individual Electro-Inactive Particles
Published on: August 4, 2023
Rate Profiling the Impact of Remote Functional Groups on the Redox-Relay Heck Reaction
Samantha L Kraus1, Sean P Ross1, Matthew S Sigman1
1Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United States.
Abstract:
The redox-relay Heck reaction is a powerful method for the construction of enantioenriched quaternary stereocenters remote from existing functional groups. However, there has been little success in the design of site-selective alkene functionalization based on these methods. Herein, we show that experimentally determined rates can be used to train a multivariate linear regression model capable of predicting the rate of a specific relay Heck reaction, allowing for the site-selective functionalization of diene substrates.
More Related Videos
Related Concept Videos
Redox Reactions
Redox Reactions
Redox Equilibria: Overview
Ladder Diagrams: Redox Equilibria
Consider the Fe3+/Fe2+ half-reaction, which has a standard-state potential of +0.771 V. At potentials more positive than +0.771 V, Fe3+ predominates, whereas Fe2+...
Balancing Redox Equations
Redox Titration: Other Oxidizing and Reducing Agents

