Rational design of flower-like Co-Zn LDH@Co(H₂PO₄)₂ heterojunctions as advanced electrode materials for...

Layered double hydroxides (LDHs) with high theoretical specific capacity have been considered as one of the most promising candidates for high-performance supercapacitors. However, the low electronic conductivity and insufficient active sites hinder the further large-scale application of bulk LDHs. Here, we successfully synthesized heterostructured Co-Zn LDH@Co(H₂PO₄)₂ nanoflowers by a simple hydrothermal method. As the amount of Co(H₂PO₄)₂ in the whole heterostructure increases, the nanosheets steadily evolve into nanoflowers with a high surface area, providing more electrochemically active sites. Moreover, the built-in electric field formed between Co-Zn LDH and Co(H₂PO₄)₂ improves the conductivity of the composite electrode. As a result, the as-prepared Co-Zn LDH@Co(H₂PO₄)₂ shows a high specific capacity of 919 C g^-1 at a current density of 1 A g^-1. A hybrid supercapacitor (HSC) with activated carbon (AC) as the negative electrode and Co-Zn LDH@Co(H₂PO₄)₂ as the positive electrode delivers an energy density of 30.4 W h kg^-1 at a power density of 400 W kg^-1, and 95.3% of the initial capacity is retained after 5000 cycles. This study provides a novel synthesis strategy for constructing heterojunctions to enhance the energy storage properties of LDH-based materials.