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Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

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Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
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Introduction to Electrolytes01:33

Introduction to Electrolytes

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In humans, electrolytes play a vital role in various physiological processes. Balancing electrolyte levels is essential for normal body functions; their imbalance can be life-threatening. The major electrolytes include sodium, potassium, chloride, calcium, phosphate, and bicarbonate. They are primarily involved in physiological processes, such as nerve signal transmission, membrane trafficking, muscle contraction, buffering body fluids, and balancing water levels in the body.
Role of Sodium
One...
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Electrolysis03:00

Electrolysis

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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
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Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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Electrodeposition01:08

Electrodeposition

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Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
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Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

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Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
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Updated: Nov 12, 2025

Electrochemical Detection of Deuterium Kinetic Isotope Effect on Extracellular Electron Transport in Shewanella oneidensis MR-1
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Localized high concentration electrolytes decomposition under electron-rich environments.

Yu Zheng1, Perla B Balbuena1

  • 1Department of Chemical Engineering, Texas A&M University, College Station, Texas 77843, USA.

The Journal of Chemical Physics
|March 16, 2021
PubMed
Summary
This summary is machine-generated.

Understanding electrolyte decomposition is key for stable solid-electrolyte interphase (SEI) layers in lithium-metal batteries. This study reveals lithium bis(fluorosulfonyl)imide and tris(2,2,2-trifluoroethyl)orthoformate decompose readily, while 1,2-dimethoxyethane remains stable.

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Area of Science:

  • Electrochemistry
  • Materials Science
  • Computational Chemistry

Background:

  • Stable solid-electrolyte interphase (SEI) formation is crucial for lithium-metal anode performance.
  • Limited understanding exists regarding electrolyte component decomposition mechanisms during SEI formation.

Purpose of the Study:

  • Investigate the reactivity and decomposition pathways of lithium bis(fluorosulfonyl)imide (LiFSI), 1,2-dimethoxyethane (DME), and tris(2,2,2-trifluoroethyl)orthoformate (TFEO) in mixed solvent electrolytes.
  • Characterize the energetics and activation barriers of key decomposition reactions.

Main Methods:

  • Computational simulations supplying excess electrons to electrolyte components.
  • Analysis of reaction mechanisms, including salt reduction, diluent decomposition, and anion-mediated reactions.
  • Thermodynamic and kinetic characterization of identified reaction pathways.

Main Results:

  • Lithium bis(fluorosulfonyl)imide (LiFSI) undergoes initial four-electron reduction.
  • Tris(2,2,2-trifluoroethyl)orthoformate (TFEO) decomposes via a six-electron pathway, with anion-attack mechanisms identified.
  • 1,2-dimethoxyethane (DME) demonstrates significant stability against electron reduction.
  • Most investigated decomposition reactions are thermodynamically favorable with low activation barriers.

Conclusions:

  • The study elucidates specific decomposition mechanisms for LiFSI and TFEO in Li-metal battery electrolytes.
  • DME exhibits superior electrochemical stability compared to LiFSI and TFEO under reducing conditions.
  • Findings provide insights into SEI formation and guide electrolyte design for improved battery performance.