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Polymers: Molecular Weight Distribution01:10

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For any given polymer, the weight average molecular weight (Mw) is higher than, if not equal to, the number average molecular weight (Mn). The only situation in which the weight average molecular weight and the number average molecular weight are equal is when a polymer consists only of chains with equal molecular weight. However, this never happens in a synthetic polymer, since it is difficult to control the polymerization process up to a molecular level with accuracy to a hundred percent.
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Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
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The fluid mosaic model was first proposed as a visual representation of research observations. The model comprises the composition and dynamics of membranes and serves as a foundation for future membrane-related studies. The model depicts the structure of the plasma membrane with a variety of components, which include phospholipids, proteins, and carbohydrates. These integral molecules are loosely bound, defining the cell’s border and providing fluidity for optimal function.
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Polymer Classification: Stereospecificity01:26

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Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
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Related Experiment Video

Updated: Nov 12, 2025

Combining Microfluidics and Microrheology to Determine Rheological Properties of Soft Matter during Repeated Phase Transitions
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Combining Microfluidics and Microrheology to Determine Rheological Properties of Soft Matter during Repeated Phase Transitions

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Viscoelastic phase separation model for ternary polymer solutions.

Kenji Yoshimoto1, Takashi Taniguchi1

  • 1Department of Chemical Engineering, Kyoto University, Kyoto 615-8510, Japan.

The Journal of Chemical Physics
|March 16, 2021
PubMed
Summary
This summary is machine-generated.

Viscoelastic phase separation in ternary polymer solutions forms network structures. The solvent moves freely, influencing phase separation dynamics in these complex mixtures.

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Area of Science:

  • Polymer Science
  • Materials Science
  • Physical Chemistry

Background:

  • Viscoelastic phase separation (VPS) in polymer solutions typically results in a polymer-rich phase forming a network structure, even when it's a minor phase.
  • This phenomenon is driven by polymer dynamics, specifically chain entanglement, and has been extensively studied in binary systems.
  • Understanding VPS in multicomponent systems, however, remains a challenge.

Purpose of the Study:

  • To develop a new model for viscoelastic phase separation in ternary polymer solutions (polymer, solvent, nonsolvent).
  • To investigate the phase separation mechanism and dynamics in these ternary systems.
  • To provide insights relevant to the manufacturing of polymeric separation membranes.

Main Methods:

  • Development of a novel viscoelastic phase separation model for ternary polymer solutions.
  • Computational simulations to analyze the phase separation process and resulting structures.
  • Analysis of polymer dynamics and solvent mobility within the ternary mixture.

Main Results:

  • The ternary bulk system exhibits network-like structure formation during phase separation, similar to binary systems.
  • A key difference in dynamics was observed: the solvent, with affinity to both polymer and nonsolvent, moves freely between phases.
  • Simulation results elucidate the specific mechanisms governing phase separation in ternary polymer solutions.

Conclusions:

  • Viscoelastic phase separation in ternary polymer solutions leads to network structures via mechanisms analogous to binary systems.
  • The mobility of the solvent plays a crucial role in the dynamics of phase separation in ternary mixtures.
  • This study enhances the understanding of phase separation in multicomponent polymer systems, vital for membrane fabrication.