Strongly Polarized Iridium^δ--Aluminum^δ+ Pairs: Unconventional Reactivity Patterns Including CO₂ Cooperative Reductive...

The iridium tetrahydride complex Cp*IrH₄ reacts with a range of isobutylaluminum derivatives of general formula Al(iBu)(OAr)_3- (x = 1, 2) to give the unusual iridium aluminum species [Cp*IrH₃Al(ⁱBu)(OAr)] (1) via a reductive elimination route. The Lewis acidity of the Al atom in complex 1 is confirmed by the coordination of pyridine, leading to the adduct [Cp*IrH₃Al(Bu)(OAr)(Py)] (2). Spectroscopic, crystallographic, and computational data support the description of these heterobimetallic complexes 1 and 2 as featuring strongly polarized Al(III)^δ+-Ir(III)^δ- interactions. Reactivity studies demonstrate that the binding of a Lewis base to Al does not quench the reactivity of the Ir-Al motif and that both species 1 and 2 promote the cooperative reductive cleavage of a range of heteroallenes. Specifically, complex 2 promotes the decarbonylation of CO₂ and AdNCO, leading to CO (trapped as Cp*IrH₂(CO)) and the alkylaluminum oxo ([(iBu)(OAr)Al(Py)]₂(μ-O) (3)) and ureate ({Al(OAr)(Bu)[κ²-(N,O)AdNC(O)NHAd]} (4)) species, respectively. The bridged amidinate species Cp*IrH₂(μ-CyNC(H)NCy)Al(Bu)(OAr) (5) is formed in the reaction of 2 with dicyclohexylcarbodiimine. Mechanistic investigations via DFT support cooperative heterobimetallic bond activation processes.