Local and global trace plutonium contributions in fast breeder legacy soils

Trace-level plutonium in the environment often comprises local and global contributions, and is usually anthropogenic in origin. Here, we report estimates of local and global contributions to trace-level plutonium in soil from a former, fast-breeder reactor site. The measured ²⁴⁰Pu/²³⁹Pu ratio is anomalously low, as per the reduced ²⁴⁰Pu yield expected in plutonium bred with fast neutrons. Anomalies in plutonium concentration and isotopic ratio suggest forensic insight into specific activities on site, such as clean-up or structural change. Local and global ²³⁹Pu contributions on-site are estimated at (34 ± 1)% and (66 ± 3)%, respectively, with mass concentrations of (183 ± 6) fg g^-1 and (362 ± 13) fg g^-1. The latter is consistent with levels at undisturbed and distant sites, (384 ± 44) fg g^-1, where no local contribution is expected. The ²⁴⁰Pu/²³⁹Pu ratio for site-derived material is estimated at 0.05 ± 0.04. Our study demonstrates the multi-faceted potential of trace plutonium assay to inform clean-up strategies of fast breeder legacies.