Uncatalyzed and acid-aided microwave hydrothermal carbonization of orange peel waste

Orange, one of the most important fruit categories to be consumed across the world, when processed produces 50% of its weight as waste. Current waste management options for orange peel waste are inadequate to use the waste in wholesome and its disposal might lead to other environmental concerns. Here, we present microwave hydrothermal carbonization as an alternative to utilize the orange peel waste. Further, using citric acid to catalyze the microwave hydrothermal carbonization resulted in 30% higher maximal yield of hydrochar, and the hydrochar produced had better elemental, proximate and energy properties than hydrochar made during uncatalyzed microwave hydrothermal carbonization. Further, structural analysis revealed that citric acid promoted the formation of nanospheres during microwave hydrothermal carbonization. Taken together, microwave hydrothermal carbonization of orange peel waste using citric acid as a catalyst might not only help address the waste management concerns for orange peel waste, but also can produce end products of potential commercial value.