Anthropogenic impacts on isotopic and geochemical characteristics of urban streams: a case study in Wuhan, China

Urbanization and human activities have significantly modified the geochemical signatures of urban streams worldwide. However, the geochemical characteristics of urban streams in Wuhan, one of the core cities in the Yangtze River Economic Belt in China, remain largely unstudied. Here, we examined the stable isotopes and geochemistry of urban streams at 73 locations in the central districts in Wuhan during May 2019. Maps of isotopic signatures reflected a non-free-flowing state in part of the urban stream system in Wuhan. A lower DO and a higher EC level were found in urban streams relative to the adjacent Yangtze River. The Na⁺, K⁺, and Cl^- concentrations in urban streams were > 3.0 times as high as those in the Yangtze River, and there was a slight increasing trend between 1.1 and 1.4 times for other major ions. The mildly elevated Fe concentration (1.3 times) and markedly elevated Mn concentration (> 5.0 times) were observed in urban streams. Spearman's correlation analysis indicated strong positive bivariate correlations among Na⁺, K⁺, and Cl^- in urban streams, and an urban geochemical principal component was identified by principal component analysis. Plotting Na/(Na + Ca) versus total dissolved solids (TDS) indicated a potential risk of "urban stream syndrome." These findings can enhance the knowledge of anthropogenic impacts on current urban stream water quality and provide reference for the restoration and improvement of water ecology functions of the urban stream system in Wuhan.