Related Experiment Video
Updated: Nov 11, 2025
Combining Microfluidics and Microrheology to Determine Rheological Properties of Soft Matter during Repeated Phase Transitions
Published on: April 19, 2018
Rheology of protein-stabilised emulsion gels envisioned as composite networks. 2 - Framework for the study of
Marion Roullet1, Paul S Clegg2, William J Frith3
1Unilever R& D Colworth, Sharnbrook, Bedford MK44 1LQ, UK; School of Physics and Astronomy, University of Edinburgh, Peter Guthrie Tait Road, Edinburgh EH9 3FD, UK.
Hypothesis:
The aggregation of protein-stabilised emulsions leads to the formation of emulsion gels. These soft solids may be envisioned as droplet-filled matrices. Here however, it is assumed that protein-coated sub-micron droplets contribute to the network formation in a similar way to proteins. Emulsion gels are thus envisioned as composite networks made of proteins and droplets.
Experiments:
Emulsion gels with a wide range of composition are prepared and their viscoelasticity and frequency dependence are measured. Their rheological behaviours are then analysed and compared with the properties of pure gels presented in the first part of this study.
Findings:
When the concentrations of droplets and protein are expressed as an effective volume fraction, the rheological behaviour of emulsion gels is shown to depend mostly on the total volume fraction, while the composition of the gel indicates its level of similarity with either pure droplet gels or pure protein gels. These results help to form an emerging picture of protein-stabilised emulsion gel as intermediate between droplet and protein gels. This justifies a posteriori the hypothesis of composite networks, and opens the road for the formulation of emulsion gels with fine-tuned rheology.
