Highly Stretchable, Adhesive, and Self-Healing Silk Fibroin-Dopted Hydrogels for Wearable Sensors

In recent years, the preparations of flexible electronic devices have attracted great attention. Here, a simple one-pot method of thermal polymerization is introduced to fabricate silk fibroin-dopted hydrogels (SFHs), which are both chemically and physically cross-linked by acrylamide (AM), acrylic acid (AA), and silk fibroin (SF). The addition of SF can effectively enhance the mechanical property of the SFH_12% by 59% compared with SFH_0% . Taking the advantage of its wide working range of stress (about 0.455-568.9 kPa), the SFH can work as a resistance-type pressure sensor to monitor different human motions. What is more, the excellent adhesion, about 75.17 N m^-1 of SFH_46% enables it to fit tightly to other objects during the testing, which significantly reduces the loss of small signals due to poor fit. In addition, the SFH demonstrates excellent self-healing property without requiring external excitation and a sensitive temperature response in the range of -10 to 60 °C. The SFH is expected to be applied in the field of electronic skin, soft robots, and other flexible electronic products as well as speech recognition.