Related Experiment Video
Updated: Nov 11, 2025

Employing Pressurized Hot Water Extraction PHWE to Explore Natural Products Chemistry in the Undergraduate Laboratory
Published on: November 7, 2018
An equilibrium desorption model for the strength and extraction yield of full immersion brewed coffee
Jiexin Liang1, Ka Chun Chan2, William D Ristenpart3
1Department of Food Science and Technology, University of California, Davis, One Shields Avenue, Davis, CA, 95616, USA.
Abstract:
The sensory qualities of brewed coffee are known to be strongly correlated with the total dissolved solids (TDS) and extraction yield (E) of the brew. Here, we derive a predictive model for the TDS and E of full immersion brewed coffee using a pseudo-equilibrium desorption approach. Assuming a single, species-averaged equilibrium constant [Formula: see text] yields theoretical predictions indicating that the TDS is approximately inversely proportional to the water/coffee mass brew ratio, while E is independent of the brew ratio. Our experimental results strongly accord with both theoretical predictions, and indicate that E is approximately 21% over a wide range of brew ratios. An analysis of the standard oven-drying method for measuring E indicates that it yields significant underestimates of the true value at equilibrium, due to retained brew within the spent moist grounds. We further demonstrate that [Formula: see text] is insensitive to grind size, roast level, and brew temperature over the range 80-99 °C. Taken together, our results indicate that full immersion brewing offers precise control over the TDS at equilibrium but little control over E, and that practitioners should pay careful attention to their brew ratio as the most important parameter for full-immersion brewing.
Related Concept Videos
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
Distillation: Vapor–Liquid Equilibria
Theories of Dissolution: Diffusion Layer Model
This process starts with a thin layer, saturated with the drug, forming at the interface between the solid and liquid. The solute then diffuses from this layer into the main solution. The Noyes-Whitney equation suggests that the rate of dissolution relies on the diffusion...
Solution Equilibrium and Saturation
Extraction: Advanced Methods
Volatilization

