Enhanced Supercapacitor Performance Using a Co₃ O₄ @Co₃ S₄ Nanocomposite on Reduced Graphene Oxide/Ni Foam Electrodes

To avoid an enormous energy crisis in the not-too-distant future, it be emergent to establish high-performance energy storage devices such as supercapacitors. For this purpose, a three-dimensional (3D) heterostructure of Co₃ O₄ and Co₃ S₄ on nickel foam (NF) that is covered by reduced graphene oxide (rGO) has been prepared by following a facile multistep method. At first, rGO nanosheets are deposited on NF under mild hydrothermal conditions to increase the surface area. Subsequently, nanowalls of cobalt oxide are electro-deposited on rGO/Ni foam by applying cyclic-voltammetry (CV) under optimized conditions. Finally, for the synthesis of Co₃ O₄ @Co₃ S₄ nanocomposite, the nanostructure of Co₃ S₄ was fabricated from Co₃ O₄ nanowalls on rGO/NF by following an ordinary hydrothermal process through the sulfurization for the electrochemical application. The samples are characterized by using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The obtained sample delivers a high capacitance of 13.34 F cm^-2 (5651.24 F g^-1 ) at a current density of 6 mA cm^-2 compared to the Co₃ O₄ /rGO/NF electrode with a capacitance of 3.06 F cm^-2 (1230.77 F g^-1 ) at the same current density. The proposed electrode illustrates the superior electrochemical performance such as excellent specific energy density of 85.68 W h Kg^-1 , specific power density of 6048.03 W kg^-1 and a superior cycling performance (86% after 1000 charge/discharge cycles at a scan rate of 5 mV s^-1 ). Finally, by using Co₃ O₄ @Co₃ S₄ /rGO/NF and the activated carbon-based electrode as positive and negative electrodes, respectively, an asymmetric supercapacitor (ASC) device was assembled. The fabricated ASC provides an appropriate specific capacitance of 79.15 mF cm^-2 at the applied current density of 1 mA cm^-2 , and delivered an energy density of 0.143 Wh kg^-1 at the power density of 5.42 W kg^-1 .