Enhanced oxygen barrier properties of poly(lactic acid) via oxygen scavenging strategy combining with uniaxial...

Poly(lactic acid) (PLA) films with significantly enhanced mechanical and oxygen barrier properties were obtained via oxygen scavenging strategy combining with uniaxial stretching. In this study, PLA was melt blended with 3 phr of hydroxy-terminated polybutadiene (HTPB) and different contents of acetyl(tributyl citrate) (ATBC) and cobalt neodecanoate. It was then followed by compression molding and uniaxial stretching. After uniaxial stretching, the crystallinity of all films was significantly improved, which contributed to the enhancement in the oxygen barrier performance of composite materials. The morphological analysis carried out using scanning electron microscopy (SEM) revealed that ATBC could obviously promote the dispersion of HTPB in PLA. Overall, the blend films showed a decrease in the oxygen permeability coefficient as compared with the neat PLA film, which reached a similar level to oriented PET film. The optical and mechanical properties of the blend films with ATBC also improved considerably. This work provides a method to prepare high-crystalline polymers with superior gas-barrier properties having great potential for use in high-barrier applications, such as polymers for oxygen-sensitive food packaging.