Facile Use of Silver Nanoparticles-Loaded Alumina/Silica in Nanofluid Formulations for Enhanced Catalytic Performance...

The introduction of toxic chemicals into the environment can result in water pollution leading to the degradation of biodiversity as well as human health. This study presents a new approach of using metal oxides (Al₂O₃ and SiO₂) modified with a plasmonic metal (silver, Ag) nanoparticles (NPs)-based nanofluid (NF) formulation for environmental remediation purposes. Firstly, we prepared the Al₂O₃ and SiO₂ NFs of different concentrations (0.2 to 2.0 weight %) by ultrasonic-assisted dispersion of Al₂O₃ and SiO₂ NPs with water as the base fluid. The thermo-physical (viscosity, activation energy, and thermal conductivity), electrical (AC conductivity and dielectric constant) and physical (ultrasonic velocity, density, refractive index) and stability characteristics were comparatively evaluated. The Al₂O₃ and SiO₂ NPs were then catalytically activated by loading silver NPs to obtain Al₂O₃/SiO₂@Ag composite NPs. The catalytic reduction of 4-nitrophenol (4-NP) with Al₂O₃/SiO₂@Ag based NFs was followed. The catalytic efficiency of Al₂O₃@Ag NF and SiO₂@Ag NF, for the 4-NP catalysis, is compared. Based on the catalytic rate constant evaluation, the catalytic reduction efficiency for 4-NP is found to be superior for 2% weight Al₂O₃@Ag NF (92.9 × 10^-3 s^-1) as compared to the SiO₂@Ag NF (29.3 × 10^-3 s^-1). Importantly, the enhanced catalytic efficiency of 2% weight Al₂O₃@Ag NF for 4-NP removal is much higher than other metal NPs based catalysts reported in the literature, signifying the importance of NF formulation-based catalysis.