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Updated: Nov 10, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Water-Mediated Catalytic Decarboxylation Enabled Polysubstituted Furans and Allylic Alcohols with Exclusive
Yulian Yang1,2, Linhong Zuo2, Kun Wei1
1School of Biology and Biological Engineering, South China University of Technology, Guangzhou 510006, China.
Abstract:
A water-mediated catalytic decarboxylation process toward the formation of polysubstituted furans and (E)-allylic alcohols has been reported. This protocol features wide functional group tolerance, easy operation, and only CO2-byproduct generation. These reactions can be performed on a large scale open to air under extremely ambient conditions. A range of control experiments revealed the crucial role of the water for the successful conversions as well as the origin of the chemoselectivity and exclusive stereoselectivity.
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