Thiol-methyl-modified magnetic microspheres for effective cadmium (II) removal from polluted water

For effective removal of cadmium (II) (Cd(II)) from polluted water, a magnetic adsorbent of Fe₃O₄@SiO₂ core-shell microspheres modified with methyl-protected thiol groups (Fe₃O₄@SiO₂-SH-Protected) was synthesized and characterized by scanning electron, transmission electron, energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopies, as well as X-ray diffraction, Raman spectroscopy, and magnetic measurements. Characterization results showed that thiol groups on the surface of Fe₃O₄@SiO₂ material were protected to avoid disulfide formation. Batch adsorption experiments were conducted by varying the contact time, initial pH, solid-liquid ratio, temperature, Cd(II) concentrations, and interfering cations. Fe₃O₄@SiO₂-SH-Protected material exhibited much higher adsorption capacity than Unprotected forms and other adsorbents due to methyl group protection. The maximum adsorption capacity calculated from the Langmuir fitting was 27.5 mg·g^-1 (pH 7, 25 °C), and the adsorption kinetics followed a pseudo-second-order model, and adsorption mainly dominated by film diffusion processes. Thermodynamic parameters indicated that the adsorption process was a spontaneous, endothermic, and positive entropic process. Cd(II)-loaded on the adsorbent was easily desorbed with 0.1 M HCl and the adsorbent stable in 0.1 M HCl for long times, showing good reusability and stability.