Branching TiO₂nanowire arrays for enhanced ethanol sensing

Nanostructure modulation is effective to achieve high performance TiO₂-based gas sensors. We herein report a wet-chemistry route to precipitate directly branched TiO₂nanowire arrays on alumina tubes for gas sensing applications. The optimized branched TiO₂nanowire array exhibits a response of 9.2 towards 100 ppm ethanol; whilst those of the pristine TiO₂nanowire array and the branched TiO₂nanowire powders randomly distributed are 5.1 and 3.1, respectively. The enhanced response is mainly contributed to the unique porous architecture and quasi-aligned nanostructure, which provide more active sites and also favor gas migration. Phase junctions between the backbone and the branch of the branched TiO₂nanowire arrays help the resistance modulation as a result of potential barriers. The facile precipitation of quasi-aligned arrays of branched TiO₂nanowires, which arein situgrown on ceramic tubes, thus provides a new economical synthetic route to TiO₂-based sensors with excellent properties.