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Updated: Nov 9, 2025

Combining Microfluidics and Microrheology to Determine Rheological Properties of Soft Matter during Repeated Phase Transitions
Published on: April 19, 2018
Two modes of cluster dynamics govern the viscoelasticity of colloidal gels
Jae Hyung Cho1, Irmgard Bischofberger1
1Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
Abstract:
Colloidal gels formed by strongly attractive particles at low particle volume fractions are composed of space-spanning networks of uniformly sized clusters. We study the thermal fluctuations of the clusters using differential dynamic microscopy by decomposing them into two modes of dynamics, and link them to the macroscopic viscoelasticity via rheometry. The first mode, dominant at early times, represents the localized, elastic fluctuations of individual clusters. The second mode, pronounced at late times, reflects the collective, viscoelastic dynamics facilitated by the connectivity of the clusters. By mixing two types of particles of distinct attraction strengths in different proportions, we control the transition time at which the collective mode starts to dominate, and hence tune the frequency dependence of the linear viscoelastic moduli of the binary gels.
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