Molybdenum Oxide Supported on Ti₃AlC₂ is an Active Reverse Water-Gas Shift Catalyst

MAX phases are layered ternary carbides or nitrides that are attractive for catalysis applications due to their unusual set of properties. They show high thermal stability like ceramics, but they are also tough, ductile, and good conductors of heat and electricity like metals. Here, we study the potential of the Ti₃AlC₂ MAX phase as a support for molybdenum oxide for the reverse water-gas shift (RWGS) reaction, comparing this new catalyst to more traditional materials. The catalyst showed higher turnover frequency values than MoO₃/TiO₂ and MoO₃/Al₂O₃ catalysts, due to the outstanding electronic properties of the Ti₃AlC₂ support. We observed a charge transfer effect from the electronically rich Ti₃AlC₂ MAX phase to the catalyst surface, which in turn enhances the reducibility of MoO₃ species during reaction. The redox properties of the MoO₃/Ti₃AlC₂ catalyst improve its RWGS intrinsic activity compared to TiO₂- and Al₂O₃-based catalysts.