Bio-nanocomposites of graphene with biopolymers; fabrication, properties, and applications

The unique properties of graphene and graphene oxide (GO) nanocomposites make them suitable for a wide range of medical, industrial, and agricultural applications. The addition of graphene or GO to a polymeric matrix can ameliorate its thermo-mechanical, electrical, and barrier characteristics. The present paper reviews the literature on graphene/GO-based bio-nanocomposites and examines the various fabrication methods, such as chemical vapor deposition, chemical synthesis, microwave synthesis, the solvothermal method, molecular beam epitaxy, and colloidal suspension. Each procedure potentially has its disadvantages, especially for mass production. Therefore, introducing an effective method for fabricating graphene on a large scale with high quality is essential. Recent studies have shown that graphene-based bio-nanocomposites are promising materials given their excellent performance in the development of biosensors, drug delivery systems, antimicrobials, modified electrodes, and energy storage systems among other applications. In this review, we evaluate the various procedures used for developing graphene/GO-based bio-nanocomposites and examine the features and applications of the related products. Furthermore, the toxicity of these compounds and attempts to uncover the optimal combinations of biopolymers and carbon nanomaterials for industrial applications will be discussed.