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Updated: Nov 8, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Recent advances in nickel-catalyzed C-C and C-N bond formation via HA and ADC reactions
Murugan Subaramanian1, Ganesan Sivakumar, Ekambaram Balaraman
1Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati, Tirupati - 517507, India. eb.raman@iisertirupati.ac.in.
Abstract:
In recent times, earth-abundant 3d-transition-metal catalysts have attracted much attention in contemporary catalysis. They have been widely employed as suitable alternatives to their counterparts noble metals. In particular, nickel catalysts provide distinctive redox properties; thus, their efficiency in sustainable organic transformations is manifold. In this review article, recent advances in nickel-catalyzed hydrogen auto-transfer (HA) and acceptorless dehydrogenative coupling (ADC) reactions for the construction of C-C and C-N bonds have been discussed.
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