Nanowired NiMoO4/NiSe2/MoSe2 prepared through in situ selenylation as a high performance supercapacitor electrode
Chengchao Wang1, Datong Wu1, Yong Qin1
1Jiangsu Key Laboratory of Advanced Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China. yzkongyong@cczu.edu.cn.
Abstract:
After in situ selenylation, hydrothermally synthesized NiMoO4 was partially converted to NiSe2 and MoSe2, and the obtained NiMoO4/NiSe2/MoSe2 nanowires were used as a supercapacitor electrode material. The specific capacitance of the nanowired NiMoO4/NiSe2/MoSe2 was significantly higher than that of NiMoO4 at a current density of 1 A g-1 (955 vs. 489 F g-1). NiMoO4/NiSe2/MoSe2 also exhibited a high capacitance retention of 86.1% after 5000 cycles at 10 A g-1. The high supercapacitive performance of NiMoO4/NiSe2/MoSe2 can be ascribed to the obvious heterointerfaces, rich defects and remarkably increased electrical conductivity after in situ selenylation of NiMoO4.
